Define a=x−2y, b=y−2z, c=z−2x. Then b,c>0 and the problem statement is b>2c. Now since
x=−7a+2b+4c,y=−7b+2c+4a,z=−7c+2a+4b
we get
S=16(x2y+y2z+z2x)+2xyz−2(x3+y3+z3)−15(xy2+yz2+zx2)=ab2+bc2+ca2−2abc=c(a−b+2cb2)2+b(b−c)2+4cb2(4c2−b2)<0
Since b,c>0, we get that 4c2<b2 and hence b>2c.