Solution:
If Alice has a card that is adjacent to one of Bob's, then Alice and Bob will play those cards as one of them is guaranteed to win. If Alice and Bob do not have any adjacent cards, since Charlie goes last, Charlie can always choose a card that will win.
Let A denote a card that is held by Alice and B denote a card that is held by Bob. We will consider the ascending order of which Alice and Bob's cards are held.
If the ascending order in which Alice and Bob's cards are held are ABAB or BABA, then Charlie cannot win. In these 2 cases, there will always be 2 consecutive cards where one is held by Alice and the other is held by Bob. Therefore, the only cases we need to consider are the ascending orders AABB, ABBA, and their symmetric cases.
In the case AABB, we must make sure that the larger card Alice holds and the smaller card Bob holds are not consecutive. Alice can thus have {1,2}, {2,3}, or {1,3}. Casework on what Bob can have yields 5 different combinations of pairs of cards Alice and Bob can hold. Since this applies to the symmetric case BBAA as well, we get 10 different combinations.
In the case ABBA, we see that Alice's cards must be {1,6} and Bob's cards must be {3,4}. Considering the symmetric case BAAB as well, this gives us 2 more combinations.
Thus, there are 12 total possible combinations of Alice's and Bob's cards such that Charlie will win regardless. The total number of ways to choose Alice's and Bob's cards is given by (26)(24)=90, so the probability that Charlie is guaranteed to win is 9012=152.