Let the quadrilateral be ABCD. We have AB+BC>AC and CD+DA>AC, so the perimeter is bigger than 2⋅AC and, similarly, bigger than 2⋅BD. Hence it's bigger than AC+BD, and the perimeter minus the sum of the diagonals is bigger than zero. Notice that this inequality is sharp: just consider a rectangle with two sides next to zero.

Now, α+β+γ+δ=180∘ and, since the radius of the circle is 1, AB=2sinγ, BC=2sinβ, CD=2sinα, AD=2sinδ, AC=2sin(β+γ)=2sin(α+δ)=sin(β+γ)+sin(α+δ) and BD=2sin(α+β)=2sin(γ+δ)=sin(α+β)+sin(γ+δ), so the difference required is
2(sinα+sinβ+sinγ+sinδ)−sin(α+δ)−sin(β+γ)−sin(α+β)−sin(γ+δ)
Notice that sin(α+γ) and sin(β+δ) are “missing”. So we will prove a stronger result, that is,
E⟹=2(sinα+sinβ+sinγ+sinδ)−sin(α+δ)−sin(β+γ)−sin(α+β)−sin(γ+δ)−sin(α+γ)−sin(β+δ)<02(sinα+sinβ+sinγ+sinδ)−sin(α+δ)−sin(β+γ)−sin(α+β)−sin(γ+δ)<sin(α+γ)+sin(β+δ)≤2
First notice that
sin(α+β)+sin(α+γ)=2sin(α+2β+γ)cos(2β−γ)=2cos(2α−δ)cos(2β−γ)
so
sinβ+sinγ−sin(α+β)−sin(α+γ)=2sin(2β+γ)cos(2β−γ)−2cos(2α−δ)cos(2β−γ)=2cos(2β−γ)(cos(2α+δ)−cos(2α−δ))=−4cos(2β−γ)sin2αsin2δ
Summing three analogous equations, we obtain
2(sinα+sinβ+sinγ)−sin(α+δ)−sin(β+γ)−sin(α+β)−sin(γ+δ)−sin(α+γ)−sin(β+δ)=−4sin2δ(cos(2β−γ)sin2α+cos(2α−γ)sin2β+cos(2β−α)sin2γ)=−4sin2δ(sin(2α+β−γ)+sin(2α−β+γ)+sin(2−α+β+γ))
Finally,
E=2sinδ−4sin2δ(sin(2α+β−γ)+sin(2α−β+γ)+sin(2−α+β+γ))=−4sin2δ(−cos2δ+sin(2α+β−γ)+sin(2α−β+γ)+sin(2−α+β+γ))=−4sin2δ(−sin(2α+β+γ)+sin(2α+β−γ)+2cos(2α−β)sin2γ)=−8sin2δ(−cos(2α+β)sin2γ+cos(2α−β)sin2γ)=−8sin2γsin2δ(−cos(2α+β)+cos(2α−β))=−16sin2αsin2βsin2γsin2δ<0
because 0<2α,2β,2γ,2δ<90∘.