Solution:
Since a regular pentagon has interior angles 108∘, we can compute ∠PDE=66∘, ∠PAE=60∘, and ∠APD=360∘−∠AED−∠PDE−∠PAE=126∘. Now observe that drawing PE divides quadrilateral PAED into equilateral triangle PAE and isosceles triangle PED, where ∠DPE=∠EDP=66∘. That is, we get PA=PE=s, where s is the side length of the pentagon.
Now triangles PAB and PED are congruent (with angles 48∘−66∘−66∘), so PD=PB and ∠PDC=∠PBC=42∘. This means that triangles PDC and PBC are congruent (side-angle-side), so ∠BPC=∠DPC.
Finally, we compute ∠BPC+∠DPC=2∠BPC=360∘−∠APB−∠EPA−∠DPE=168∘, meaning ∠BPC=84∘.