For a=4, an example of such a number is 126734895. For a=5, an example is the number 549832761. (There are other solutions as well.)
We will show that for a=3,6,7,8,9 there is no complete number with a difference number equal to 1a1a1a1a. It then immediately follows that there is also no complete number N with difference number equal to a1a1a1a1 (otherwise, we could write the digits of N in reverse order and obtain a complete number with difference number 1a1a1a1a).
For a equal to 6, 7, 8, and 9, no such number N exists for the following reason. For the digits 4, 5, and 6, there is no digit that differs by a from that digit. Since the difference number of the complete number N is equal to 1a1a1a1a, every digit of N, except the first, must be next to a digit that differs from it by a. Hence, the digits 4, 5, and 6 can only occur in the first position of N, which is impossible.
For a=3 the argument is different. If we consider the digits that differ by 3, we find the triples 1–4–7, 2–5–8, and 3–6–9. If the 1 is next to the 4 in N, the 7 cannot be next to the 4 and so the 7 must be the first digit of N. If the 1 is not next to the 4, the 1 must be the first digit of N. In the same way, either the 2 or the 8 must be the first digit of N as well. This is impossible.