## Corrected
Let's start by drawing a figure.
!
First, since AB<AC, D lies on the segment [AC] and the angle ∠MAE is obtuse. Since MC=MA, this implies that △CAM and △AME are similar if and only if △AME is isosceles at A.
Suppose that △AEM and △MCA are similar. From the first paragraph, this implies AM=AE. The lines (EM) and (AC) are parallel, so the lines (AB) and (ME) are perpendicular. Combined with the fact that AM=AE, this shows that △AMB and △ABE are symmetric with respect to (AB). Let α=∠MAB. Since M is the midpoint of [BC], we have AM=MB, which gives α=∠ABC. On the other hand, α=∠BAE=∠ABE=90∘−∠DBA=∠ADB.
Since ∠DAB=∠DMB=90∘, the points A,D,M,B are concyclic. We deduce that ∠AMB=∠ADB=α. The triangle △AMB has all three angles equal to α. Therefore, it is equilateral and α=60∘. Thus, ∠ABC=60∘.
Conversely, if ∠ABC=60∘, the same reasoning shows that △AMB and △ABE are symmetric with respect to (AB), which implies that △AME is isosceles at A. Since ∠CAM=∠AME, △AEM and △MCA are similar.