From the identity $\tan \frac{u}{2}=\frac{\sin u}{1+\cos u}$, the conditions work out to $3 \tan \frac{w}{2}=4 \tan \frac{x}{2}=5 \tan \frac{y}{2}=6 \tan \frac{z}{2}=k$. Let $a=\tan \frac{w}{2}, b=\tan \frac{x}{2}, c=\tan \frac{y}{2}$, and $d=\tan \frac{z}{2}$. Using the identity $\tan (M+N)=\frac{\tan M+\tan N}{1-\tan M \tan N}$, we obtain $\tan \left(\frac{w+x}{2}+\frac{y+z}{2}\right) =\frac{\tan \left(\frac{w+x}{2}\right)+\tan \left(\frac{y+z}{2}\right)}{1-\tan \left(\frac{w+x}{2}\right) \tan \left(\frac{y+z}{2}\right)} =\frac{\frac{a+b}{1-a b}+\frac{c+d}{1-c d}}{1-\left(\frac{a+b}{1-a b}\right)\left(\frac{c+d}{1-c d}\right)} =\frac{a+b+c+d-a b c-a b d-b c d-a c d}{1+a b c d-a b-a c-a d-b c-b d-c d}$. Because $x+y+z+w=\pi$, we get that $\tan \left(\frac{x+y+z+w}{2}\right)=0$ and thus $a+b+c+d=a b c+a b d+b c d+a c d$. Substituting $a, b, c, d$ corresponding to the variable $k$, we obtain that $k^{3}-19 k=0$. Therefore, $k$ can be only $0, \sqrt{19},-\sqrt{19}$. However, $k=0$ is impossible as $w, x, y, z$ will all be 0. Also, $k=-\sqrt{19}$ is impossible as $w, x, y, z$ will exceed $\pi$. Therefore, $k=\sqrt{19}$.