Let us find all positive integers $n$ such that the following condition holds: Given real numbers $a_1, a_2, \ldots, a_n$ and $b_1, b_2, \ldots, b_n$ satisfying $|a_k| + |b_k| = 1$ for all $k = 1, 2, \ldots, n$, there exist signs $\varepsilon_1, \varepsilon_2, \ldots, \varepsilon_n \in \{-1, 1\}$ such that:

$$\left| \sum_{i=1}^n \varepsilon_i a_i \right| + \left| \sum_{i=1}^n \varepsilon_i b_i \right| \le 1.$$

### Step-by-step Analysis

1. Understanding the Problem Constraints:

The key constraint is $|a_k| + |b_k| = 1$ for each $k$. This implies that $a_k$ and $b_k$ are points on the line segment joining $(0,1)$ and $(1,0)$ in the Cartesian plane.

2. Necessary Geometric Interpretation:

Such a condition defines $a_k$ and $b_k$ as points on the line $y = 1 - x$ for $x \in [0, 1]$.

3. Objective:

We are tasked with finding whether, for some selection of signs $\varepsilon_i$, the total effect on the sums of $a_i$ and $b_i$ does not exceed 1.

4. **Key Case of Odd $n$:**

Suppose $n$ is odd:

- Assume without loss of generality, if we consider vectors $\mathbf{a} = (a_1, a_2, \ldots, a_n)$ and $\mathbf{b} = (b_1, b_2, \ldots, b_n)$, then due to the odd nature of $n$, there exists a combination of $\varepsilon_i$ such that these two vectors can be rendered “balanced.”

- The reason being, when $n$ is odd, dividing its components between positive and negative contributions makes it easier to find a setup where the sums weighted by $\varepsilon_i$ yield the desired bound.

5. **Case $n=3$ as Example:**

- Consider $n=3$ with extreme points where $|a_k| = 0$ or $|b_k| = 0$. An assignment of $\varepsilon_i = (-1)^{i+1}$ balances the path both going towards and away symmetrically, thus one can bound the sums as required.

6. **Conclusion on Odd $n$:**

By similar reasoning as outlined, we can extend that \textbf{every odd $n \ge 3$} will ensure such a combination exists.

### Relatively Straightforward Case when $n$ is Even:

When $n$ is even, the symmetry in partitioning does not assure balance with simple alternation or straightforward symmetry. As $n$ is even, directly arranging these values risks non-positive-definite partitions, invalidating the condition.

### Final Result:

All odd integers $n \ge 3$ satisfy the condition. Therefore, it can be concluded that the solution set for $n$ is:

$$\boxed{\text{all odd integers } n \ge 3}$$

This completes the analysis for the posed problem.