Consider the equation in integers $\mathbb{Z}^2$:
$$x^2 (1 + x^2) = -1 + 21^y.$$

First, rewrite the equation as:
$$x^2 + x^4 = -1 + 21^y.$$
Thus, we have:
$$x^4 + x^2 + 1 = 21^y.$$

We're tasked with finding integer solutions $(x, y)$.

### Step-by-step Analysis:

1. **Case $x = 0$:**

Substituting $x = 0$ gives:
$$0^4 + 0^2 + 1 = 1.$$
Thus:
$$21^y = 1.$$
This implies:
$$y = 0.$$
Therefore, one solution is:
$$(x, y) = (0, 0).$$

2. **Case $x \neq 0$:**

Simplify and rearrange the equation:
$$x^2(x^2 + 1) = -1 + 21^y.$$
This suggests testing small values of $x$.

3. **Trial for $x = 1$:**

Substituting $x = 1$ gives:
$$1^2(1 + 1) + 1 = 3.$$
$$21^y = 2.$$
No integer solution for $y$.

4. **Trial for $x = 2$:**

Substituting $x = 2$ gives:
$$2^2(4 + 1) + 1 = 17.$$
$$21^y = 17.$$
No integer solution for $y$.

5. **Trial for $x = \pm 2$:**

Substituting $x = 2$ gives:
$$2^4 + 2^2 + 1 = 21.$$
Thus:
$$21^y = 21.$$
This implies:
$$y = 1.$$
Therefore, two solutions are:
$$(x, y) = (2, 1) \text{ and } (-2, 1).$$

To conclude, the integer solutions are:
$$\boxed{(0, 0), (2, 1), (-2, 1)}.$$

These steps demonstrate how $(x, y)$ values satisfy the equation $x^2(x^2 + 1) = -1 + 21^y$ in $\mathbb{Z}^2$.