By the arithmetic-harmonic mean inequality or the Cauchy-Schwarz inequality, $$(k_1 + \cdots + k_n)\left(\frac{1}{k_1} + \cdots + \frac{1}{k_n} \right) \geq n^2.$$ We must thus have $5n-4 \geq n^2$, so $n \leq 4$. Without loss of generality, we may suppose that $k_1 \leq \cdots \leq k_n$. If $n=1$, we must have $k_1 = 1$, which works. Note that hereafter we cannot have $k_1 =1$. If $n = 2$, we have $(k_1,k_2) \in \{(2,4), (3,3)\}$, neither of which work. If $n=3$, we have $k_1 +k_2 +k_3 =11$, so $2 \leq k_1 \leq 3$. Hence $$(k_1,k_2,k_3) \in \{(2,2,7),(2,3,6),(2,4,5),(3,3,5),(3,4,4)\},$$ and only $(2,3,6)$ works. If $n = 4$, we must have equality in the AM-HM inequality, which only happens when $k_1 = k_2 = k_3 = k_4 = 4$. Hence the solutions are $n = 1$ and $k_1 = 1$, $n=3$ and $(k_1,k_2,k_3)$ is a permutation of $(2,3,6)$, and $n=4$ and $(k_1,k_2,k_3,k_4) = (4,4,4,4)$.