The total central angle in a circle is 360∘.
Since the Green section has an angle at the centre of the circle of
90∘, this section corresponds
to $360∘90∘=41$ of the circle.
This means that when the spinner is spun once, the probability that it
lands on the Green section is 41.
Similarly, the probability that the spinner lands on Blue is also 41.
Since the spinner lands on one of the four colours, the probability that
the spinner lands on either Red or Yellow is $1 - 41−41=21$.