Solution:
A given pair must play with three other pairs and these plays must be in different days, so at least three days are needed. Suppose that three days suffice. Let the pair AB play against CD on day x. Then AB−DE and CD−BE cannot play on day x. Then one of the other two plays of DE (with AC and BC) must be on day x. Similarly, one of the plays of BE with AC or AD must be on day x. Thus, two of the plays in the chain BC−DE−AC−BE−AD are on day x (more than two among these cannot be on one day).
Consider the chain AB−CD−EA−BD−CE−AB. At least three days are needed for playing all the matches within it. For each of these days we conclude (as above) that there are exactly two of the plays in the chain BC−DE−AC−BE−AD−BC on that day. This is impossible, as this chain consists of five plays.
It remains to show that four days will suffice:
Day 1: AB−CD, AC−DE, AD−CE, AE−BC
Day 2: AB−DE, AC−BD, AD−BC, BE−CD
Day 3: AB−CE, AD−BE, AE−BD, BC−DE
Day 4: AC−BE, AE−CD, BD−CE.